Oxidation‐led decomposition of hexagonal boron nitride coatings on alloy substrates at 900 °C: Ti‐6Al‐4V

Hexagonal boron nitride (h‐BN) coatings on Ti‐6Al‐4V substrates undergo complete decomposition in air at 900 °C. This fate is similar to that of this ceramic material on chromia‐former alloys, and unlike that of a mass of powder treated in isolation. As the ceramic and alloy oxidize concurrently, outwardly diffusing aluminum (III) ions but not the predominant titanium (IV) ions react with the boron trioxide that forms around the h‐BN basal plane peripheries. Resultant aluminum borate is incorporated into the growing scale and the boron trioxide diffusion barrier is depleted. By this mechanism, the oxidation of h‐BN is maintained at an enhanced rate, until both this material and its oxide completely decompose. Liberated nitrogen from the oxidation of h‐BN can enter the underlying scale as a randomly distributed solute in rutile solid solution. The post‐coating oxide‐atmosphere interface comprises elongated aluminum borate crystallites protruding through at the boundaries between 3–5 at% nitrogen‐doped rutile grains. It differs significantly from that of oxidized, uncoated Ti‐6Al‐4V, which is occupied by a thin α‐alumina layer atop rutile. This interface does not change with an additional 72 h of heat‐treatment.     

Corrosion behavior of under‐, peak‐, and over‐aged 6063 alloy: A comparative study

The mechanical property of age‐hardenable Al‐alloys is governed by the state of ageing, which determines the microstructure and consequently, their corrosion behavior which is a vital aspect for a number of applications. This article presents a comparative assessment of corrosion behavior of under‐, peak‐ and over‐aged Al‐Mg‐Si alloy. Corrosion characteristics have been determined via immersion tests in 0.1 M ortho‐phosphoric acid solution and intergranular corrosion (IGC) tests. Corroded surfaces are examined by field emission scanning electron micrographs‐energy dispersive spectroscopy and 3D optical profilometer. The obtained results reveal that the corrosion rate at a specific immersion time as well as the depth of IGC increases in the order for under‐, peak‐, and over‐aged states. Irrespective of the state of ageing, corrosion loss increases linearly but the rate of corrosion decreases rapidly with increasing immersion time. The dominant mode of corrosion in under‐aged alloy is identified as localized pitting, while peak‐aged is highly susceptible to IGC in contrast extensive pitting corrosion is observed for over‐aged alloy. The observed differences in corrosion behavior are explained considering characteristics of precipitates. Formation of β (Mg₂Si) in case of over‐aged alloy and presence of inclusions like AlFeMnSi particles are found to accelerate pitting corrosion.     

微量Zr对不对称轧制Al-0.8Mg-0.9Si合金板织构及性能的影响

本文研究了微量Zr对不对称轧制Al-0.8Mg-0.9Si合金板及其相继固溶处理后的微观结构及性能的影响。结果表明：微量Zr在Al-0.8Mg-0.9Si合金中形成Al3Zr相弥散分布在基体中,在不对称轧制过程中,该化合物相对Copper{112}<111>、Brass{011}<211>、S{123}<634>、E{111}<110>和F{111}<112>等形变织构无明显影响；在随后的固溶处理过程中,轧制板材发生的再结晶使得Copper、Brass、S等形变织构的取向密度降低,但不溶的细小Al3Zr相在一定程度上抑制了不连续再结晶行为,反而使轧制过程中形成的E、F剪切织构的取向密度增加。添加微量Zr所形成的上述结构使该合金板材在固溶后获得较好的综合性能,其抗拉强度、屈强比和延伸率分别可达230MPa、0.49和9.5%以上；塑性应变比r值从0.7提高至0.84,杯突值IE由8.94提高至9.84,各向异性度|Δr|由0.15降低至0.04。     

Hierarchical Coherent Phonons in a Superatomic Semiconductor

The coupling of phonons to electrons and other phonons plays a defining role in material properties, such as charge and energy transport, light emission, and superconductivity. In atomic solids, phonons are delocalized over the 3D lattice, in contrast to molecular solids where localized vibrations dominate. Here, a hierarchical semiconductor that expands the phonon space by combining localized 0D modes with delocalized 2D and 3D modes is described. This material consists of superatomic building blocks (Re₆Se₈) covalently linked into 2D sheets that are stacked into a layered van der Waals lattice. Using transient reflectance spectroscopy, three types of coherent phonons are identified: localized 0D breathing modes of isolated superatom, 2D synchronized twisting of superatoms in layers, and 3D acoustic interlayer deformation. These phonons are coupled to the electronic degrees of freedom to varying extents. The presence of local phonon modes in an extended crystal opens the door to controlling material properties from hierarchical phonon engineering.     

Corrosion protection of aluminum alloy by epoxy coatings containing polyaniline modified graphene additives

In the study, polyaniline/reduced‐graphene oxide (PANI‐RGO) composites, fabricated by loading 2, 5, and 8wt% graphene oxide, was prepared by in‐situ emulsion polymerization and reduction. They are characterized by Fourier transform infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy. Epoxy coatings adding PANI and PANI‐RGO composites were coated on the surface of AA5083 Al alloy. The anticorrosion performance of the coatings is measured by electrochemical impedance spectroscopy and potentiodynamic polarization curve in 3.5wt% NaCl solution. The results demonstrate that the epoxy/PANI‐RGO coating exhibits a better protection against AA5083 alloy corrosion compared with the epoxy/PANI coating. Enhancement of the passivation performance of PANI was obtained by the addition of RGO into epoxy/PANI coating system.     

基于多视图立体视觉的沙堆三维尺寸测量研究

利用从运动中恢复结构方法(SFM),提出了一种基于多视图立体视觉的沙堆三维重建及三维尺寸测量方法。首先根据SFM方法的求解不稳定特点,结合光束平差法对SFM求解过程进行分析及优化;其次针对SFM重建结果为稀疏点云的问题,利用基于面片的稠密重建算法重新生成稠密的三维点云,再利用泊松算法对密集点云进行三维曲面重建;最后获得模型的三维尺寸信息。对某建筑工地的沙堆进行了三维尺寸的测量实验,实验结果验证了该方法的有效及可行性,提高了重建能力及精度,同时考虑了目标实际测量误差与重建误差,能够满足实际智能测量的应用需求。     

Eye movements and visual discomfort when viewing stereoscopic 3D content

The visual brain fuses the left and right images projected onto the two eyes from a stereoscopic 3D (S3D) display, perceives parallax, and rebuilds a sense of depth. In this process, the eyes adjust vergence and accommodation to adapt to the depths and parallax of the points they gazed at. Conflicts between accommodation and vergence when viewing S3D content potentially lead to visual discomfort. A variety of approaches have been taken towards understanding the perceptual bases of discomfort felt when viewing S3D, including extreme disparities or disparity gradients, negative disparities, dichoptic presentations, and so on. However less effort has been applied towards understanding the role of eye movements as they relate to visual discomfort when viewing S3D. To study eye movements in the context of S3D viewing discomfort, a Shifted-S3D-Image-Database (SSID) is constructed using 11 original nature scene S3D images and their 6 shifted versions. We conducted eye-tracking experiments on humans viewing S3D images in SSID while simultaneously collecting their judgments of experienced visual discomfort. From the collected eye-tracking data, regions of interest (ROIs) were extracted by kernel density estimation using the fixation data, and an empirical formula fitted between the disparities of salient objects marked by the ROIs and the mean opinion scores (MOS). Finally, eye-tracking data was used to analyze the eye movement characteristics related to S3D image quality. Fifteen eye movement features were extracted, and a visual discomfort predication model learned using a support vector regressor (SVR). By analyzing the correlations between features and MOS, we conclude that angular disparity features have a strong correlation with human judgments of discomfort.     

Probing the degenerate pattern growth of {100}<011> orientation in a directionally solidified Al-4.5 wt% Cu alloy

Degenerate pattern is a seemingly disordered morphology but it exhibits the inherently ordered crystal connected with tip-splitting and limited stability which makes it difficult to observe in the metallic system. Here we employ (100)[011] orientated planar-front seeds using directional solidification and reveal the fundamental origins of the degenerate pattern growth in an Al-4.5 wt% Cu alloy. We find that the spacing of the tip-splitting (λ) in the degenerate of the alloys followed a power law, λ∝V^−0.5, and the frequency (f) of the splitting was related to the growth velocity (V) by ƒ∝V^1.5. The dimensionless growth direction (θ/θ₀) increased monotonously and approached 0.6 with faster velocity, attributed to its anisotropy in the interface kinetics. Once growth velocity exceeded a threshold, two types of pattern transitions from degenerate to regular dendrites were proposed. One of them exhibited a random and chaotic mode and the other underwent a rotation in growth direction.     

热处理对挤压态Mg-6Gd-5Y-1Zn合金组织与性能的影响

通过对Mg-6Gd-5Y-1Zn(质量分数,%)合金在固溶和时效处理状态下显微组织和力学性能的研究发现,α-Mg基体、沿挤压方向分布的条状18R-LPSO相、少量的Mg₂₄(GdYZn)₅ 相以及细层片状的14H-LPSO相构成了挤压态合金的组成相。挤压态合金经固溶(T4)处理后,一部分18R-LPSO相溶入基体,并且基体中的14H-LPSO相伸长同时粗化。挤压态合金经过固溶加时效(T6)处理后,大量β′相从α-Mg基体中析出。T6态合金的室温力学性能最好,其屈服强度、抗拉强度及伸长率分别为272 MPa、406 MPa和6.1%。β′相沉淀也发生在挤压态合金的直接人工时效(T5)处理过程,但相比于T6处理,14H-LPSO相和β′相在基体中的体积分数均偏低。